PPE and no alcohol or tobacco. All of them, in addition to being careless were heavy smokers and drinkers. On the shoes: Moment I am dealing with pesticides of any kind, I am in rubber boots. Shoes can become a source of chemical transfer to the feet through the fabric or leather. Prior to the 2000s, PPE was not really specified. But full coverage, gloves and boots were standard for me. Anytime a mist was going to be generated such as spraying trees or spraying Daconil for coverage, I used the Organic Vapor+Mists respirator. That is what saved me from being poisoned by the organophosphate and carbamate fungicides. Add 2,4-D to the list of things to be careful of unless you want to end up with cancer later.
I remember meeting the greenskeeper at the bowling green a few years before I inherited his job. Imagine this: No shirt, shorts, no gloves or boots. He was spraying a combination of MSMA and 2,4-D on some weeds at the green with a 1 gallon sprayer. In 2016, I got a call from the club saying he was dying and if I could take over. Pancreatic/liver cancer dead in less than 6 months.